Climate change and refrigerants: Thermodynamic properties of low-GWP fluids for domestic applications and binary systems for low-temperature options

The most commonly used refrigerants are potent greenhouse gasses that can contribute to climate change. Hydro-Fluoro-Olefins are low GlobalWarming Potential fluids. A summary of our experimental research activity on the thermodynamic properties of two environmentally friendly Hydro-Fluoro-Olefins, namely R1234yf and R1234ze(E), is reported. In particular, the measurements were performed with an isochoric apparatus and the apparatus specifically built to reach temperatures down to about 100 K. The data elaboration confirms the validity of the choice and that R1234yf and R1234ze(E) can be adopted in many domestic applications. Moreover, considering the reduction of the flammability issues of R1234yf and R1234ze(E), the properties of binary systems containing these fluids and carbon dioxide were analyzed. The presented mixtures could be very interesting for low-temperature applications such as cascade cycles.